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DEFINITION: Potassium Iodate is a powerful oxidizing agent under suitable conditions, it reacts quantitatively with both iodides and iodine, arsenides, and other reducing agents.
Iodate titration can be performed in the presence of alcohol, saturated organic acid, and many other kinds of organic matter.
PRINCIPLE: The reaction between potassium iodate and reducing agents such as iodide ions or As2O3 in solutions of moderate acidity (0.12 -2M HCl) stops at the state when the iodate is reduced to iodine.
KIO3 + 5KI + 6HCl 3I2 + 6KCl + 3H2O
2KIO3 + 5H3AsO3 +2HCl I2 +5H3AsO4 +H2O +2KCl
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Titration with Potassium Iodide Notes Includes Topics
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- Definitions
- Principles
- Standardization of 0.05M Potassium Iodate
- Application
- Assay of Potassium Iodate
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