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The principle of conductometric titration is based on the fact that during the titration, one of the ions is replaced by the other and invariably these two ions differ in the ionic conductivity with the result that the conductivity of the solution varies during titration.
The equivalence point may be located graphically by plotting the change in conductance as a function of the volume of titrant added.
To reduce the influence of errors in the conductometric titration to a minimum, the angle between the two branches of the titration curve should be as small as possible. If the angle is very obtuse, a small error in the conductance data can cause a large deviation. The following approximate rules will be found
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- Introduction
- Strong Acids with a Strong Base, e.g. HCl with NaOH
- Weak Acid with a Strong Base, e.g. acetic acid with NaOH
- Strong Acid with a Weak Base, e.g. sulphuric acid with dilute ammonia
- Weak Acid with a Weak Base
- A mixture of a Strong Acid and a Weak Acid vs. a Strong Base or a Weak Base
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