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PRINCIPLE: Ce(SO4)2 .2(NH4)2. SO4. 2H2O in an H2SO4 medium can function as a strong oxidizing agent and have a high oxidation potential. Sufficient H2SO4 is used to prevent hydrolysis and precipitation of basic salts.
Ceric Ammonium Sulphate is a salt of suitable solubility for the precipitation of the standard solution and has the approximate formula Ce(SO4)2.2(NH4)2. SO4. 2H2O.
But the solution has to be standardized against a solution of As2O3. Since Ceric Ammonium Sulphate is a strong oxidizing agent we can determine various reducing substances by simple titration. In the presence of a reducing agent it undergoes reduction to the cerous state for example:
Ce(SO4)2 + 2FeSO4. Ce(SO4)3 + 2Fe(SO4)3
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- Standardization of 0.1M Ce(SO4)2
- IP or Equivalent factors
- Calculation, Application
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