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Dilute alcohols are made from 95% alcohol which contains 95 parts by volume of ethyl alcohol and 5 parts by volume of water. Following changes occur when alcohol gets mixed with water.
(a) There is a sudden temperature rise.
(b) There is a contraction in volume.
The appearance of turbidity in the solution is because the solubility of air is more in alcohol than in water. When the alcohol is diluted with water, minute bubbles of air get evolved from the alcohol and make the solution turbid.
So when the alcohol is diluted with water, it is necessary to cool the mixture to about 20°C and then the final volume is made up. The formula used is:
Quantity of stronger solution to be used X concentration of alcohol used
= Quantity required to prepare X Concentration of alcohol required.
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